|
|
4-nitrobenzoate + CoA + ATP <=> 4-nitrobenzoyl-CoA + AMP + diphosphate
|
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.33
4-chlorobenzoate---CoA ligase
6.2.1.M32
|
–
–
–
|
| |
BRENDA:
BS324
MetaCyc:
RXN-20207
|
|
|
|
holo-[aureothin_polyketide_synthase] + 4-nitrobenzoyl-CoA + malonyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> (8E,10E)-2,4,8,10-tetramethyl-11-(4-nitrophenyl)-3,5-dioxoundeca-8,10-dienoyl-[aureothin_polyketide_synthase] + CO2 + CoA + NADP+ + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20206
|
|
|
|
S-adenosyl-L-methionine + demethylluteothin <=> S-adenosyl-L-homocysteine + luteothin + H+
|
2.1.1.353
demethylluteothin O-methyltransferase
|
–
|
| |
BRENDA:
BR52682
KEGG:
R12336
MetaCyc:
RXN-20209
|
|
|
|
4-Aminobenzoic_acid + O2 + reduced_acceptor <=> 4-nitrobenzoate + H2O + acceptor
|
1.14.99.ag
|
–
|
| |
MetaCyc:
RXN-20202
|
|
|
|
luteothin + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> aureothin + H2O + oxidized_ferredoxin
|
1.14.15.37
luteothin monooxygenase
|
–
|
| |
BRENDA:
BR52678
KEGG:
R12324
MetaCyc:
RXN-20210
|
|
|
|
(8E,10E)-2,4,8,10-tetramethyl-11-(4-nitrophenyl)-3,5-dioxoundeca-8,10-dienoyl-[aureothin_polyketide_synthase] <=> demethylluteothin + holo-[aureothin_polyketide_synthase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20208
|
|
